Everything about The Dithionate totally explained
The
dithionate anion, S
2O
62−, is a
sulfur oxoanion derived from
dithionic acid, H
2S
2O
6. Its
chemical formula is sometimes written in a semistructural format, as [O
3SSO
3]
2−.
The sulfur atoms of the dithionate ion are in the +5
oxidation state due to the presence of the S-S bond. Generally dithionates form stable compounds that are not readily oxidised or reduced. Strong oxidants oxidise them to
sulfates and strong reducing agents reduce them to
sulfites and
dithionites. Aqueous solutions of dithionates are quite stable and can be boiled without decomposition .
The γ irradiation of crystalline dithionates produces SO
3− radical ions. The unpaired electron in the SO
3− radical can be detected with
electron paramagnetic resonance and barium dithionate has been proposed as the basis for a radiation
dosimeter
The dithionate ion can act as a bidentate
ligand .
The structure of the dithionate ion in the solid state is staggered in Na
2S
2O
6.2H
2O whereas in the anyhydrous potassium salt it's nearly eclipsed
.
Compounds
Compounds containing the dithionate ion include:
Further Information
Get more info on 'Dithionate'.
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